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My romance with the transuranium elements started 63 years ago, in 1934, soon
after I became a chemistry graduate student at the University of California,
Berkeley. These were the undiscovered elements with atomic numbers greater than
92 (the atomic number of uranium), the heaviest naturally occurring element.
We (the transuranium elements and I) were first introduced at the weekly
chemistry seminar on nuclear science held in venerable Gilman Hall. Actually, I
was introduced to what were thought to be the transuranium elements. I read
articles by Enrico Fermi and coworkers about the induced radioactivities
observed when elements such as uranium were bombarded with neutrons. Since some
were published in their native Italian, they were a challenge to decipher.
These induced radioactivities were, of course, produced in trace
(unweighable)
quantities, so radiochemistry methods were needed. For guidance, researchers
predicted the chemical properties using the periodic table as it was then known.
The heaviest natural elements, thorium, protactinium, and uranium (atomic
numbers 90, 91, and 92), were placed in that table just below the sixth-period
"transition elements"-hafnium, tantalum, and tungsten (in these
elements, the "5d" electron shell is being filled). Thus it was
assumed that the 6d electron shell was being filled in these heaviest elements,
and the chemical properties of the transuranium elements, the undiscovered
elements 93, 94, 95, and 96, would be homologous with the 5d elements
immediately above them in the periodic table, rhenium, osmium, iridium, and
platinum.
The limited chemical identification experiments of Fermi and coworkers seemed
consistent with this view. The work of Otto Hahn, Lise Meitner, and Fritz
Strassman in Berlin seemed to further confirm it.
Little did we know then how we were being misled by accepting what was
easiest to accept. I bought this interpretation "hook, line, and
sinker." In the fall of 1936, I described the work and interpretation of
Otto Hahn and coworkers during a required graduate student talk to the chemistry
faculty, staff, graduate students, and visiting scientists.
Then in January 1939, the bubble burst! At the physics journal club meeting,
we heard something extraordinary. Niels Bohr, who had arrived in New York the
previous week, brought news from Otto Hahnšs laboratory that the
neutron-bombardment of uranium produced isotopes of light elements, like barium
and lanthanum. The meaning was simple: the uranium had been split approximately
in half, and all the radioactive "transuranium" isotopes studied by
Hahn, Strassman, and Meitner during the previous four years were actually
isotopes from the middle of the periodic table.
This was exciting! After the seminar, I walked the Berkeley streets for
hours, chagrined that I hadnšt recognized that the "transuranium
elements" in which I had been so interested were nothing of the kind. I
felt stupid for failing to admit the possibility. Subsequent work showed that
the radioactivities that had been ascribed to transuranium elements were
actually due to fission products!
With poetic justice, the actual discovery of the first transuranium element
resulted from experiments aimed at understanding the fission process. In 1940,
Edwin M. McMillan and Philip H. Abelson showed that a radioactive product of the
bombardment of uranium with neutrons was an isotope of element 93, with a mass
number 239 (23993). The isotope 23993, a negative beta-particle emitter, should
decay to the product 23994, but they were unable to observe this daughter
product because of its long half-life.
McMillan then started looking for a shorter-lived isotope of element 94
through the deuteron bombardment of uranium. When McMillan was called to MIT for
war work, I continued this quest with the help of my graduate student Arthur C.
Wahl and another instructor in chemistry at Berkeley, Joseph W. Kennedy. We
succeeded on the night of February 2324, 1941, in chemically identifying
(i.e., discovering) element 94 (the isotope 23994) in room 307, Gilman Hall
(designated as a National Historic Landmark on the 25th anniversary of the
discovery). Most importantly, we found that the chemical properties of element
94 weren't like those predicted from the periodic table of that time (i.e., not
like osmium), but were chemically similar to uranium. Joined by physicist Emilio
Segrč, we soon identified 23994 and, most importantly, demonstrated that it was
fissionable by slow neutrons.
Following McMillan's suggestion for naming element 93 "neptunium"
(after Neptune, the first planet beyond Uranus), with the chemical symbol Np,
Wahl and I suggested "plutonium" (after Pluto, the next planet) for
element 94. We first debated whether the name should be "plutium" or
"plutonium," the sound of which we liked better. Although the chemical
symbol might have been "Pl," we liked the sound of "Pu," for
the reason you might suspect, and therefore decided on "Pu."
I had the pleasure of meeting for the first time Clyde
Tombaugh, the
discoverer of the planet Pluto, in Albuquerque, New Mexico, on June 9, 1991. At
that time, he told me he had also considered naming his planet after the Greek
god Cronus or Roman goddess Minerva (rather than after Pluto). In that case, I
suppose we would have given element 94 the name "cronium" or "minervium,"
and therefore, people throughout the world would never have heard the word
"plutonium" which is so much in the news today.
The chemical properties of neptunium and plutonium were found to be similar
to those of uranium and quite unlike those of rhenium and osmium, which,
according to the existing periodic table, they should have resembled. Thus we
concluded that a new series of 14 rare-earth-like elements, starting at uranium,
would be the "uranide" (uranium-like) series, just as the 14
rare-earth elements were known as the "lanthanide" (lanthanum-like)
series.
Wrong again!
Soon after Pearl Harbor and the U.S. entry into World War II, I moved to the
wartime Metallurgical Laboratory of the University of Chicago. Here, we solved
many of the problems attendant with plutonium-239 production, and I turned my
attention to the quest for the next two transuranium elements, 95 and 96. I was
joined in the endeavor by my colleagues Albert Ghiorso, Ralph A. James, and Leon
O. (Tom) Morgan. But when we predicted the chemical properties on the basis of
the "uranide" concept, we failed to make any identification of our
transmutation products.
We weren't successful until I suggested that we needed a bold revision of the
periodic table in order to make correct predictions of the chemical properties
of elements 95 and 96. I wrote a secret report in July 1944, suggesting that
thorium, protactinium, and uranium be removed from the body of the periodic
table and placed as the beginning of a "transition" series, analogous
to the lanthanide (rare-earth) elements, in a separate row at the bottom. Thus
the 14 elements beginning with thorium (elements 90103), would become the
"actinide" elements (by analogy with the "lanthanide"
elements). They would then show the necessary element-by-element analogy with
the lanthanide elements (5871).
Thus element 95 would be chemically similar to the lanthanide element
europium (63) and element 96 would be chemically similar to gadolinium (64).
Using this concept, in 1944 and 1945, we synthesized and chemically identified
elements 95 and 96, by analogy with their rare earth homologues, europium
(element 63) and gadolinium (element 64). The new elements were subsequently
named americium (95) and curium (96) by analogy with the naming of their
homologues. This bold revision of the periodic table was a hard sell. When I
showed it to some world-renowned inorganic chemists, I was advised not to
publish it-such an act would "ruin my scientific reputation."
However, I did publish it after the war, and it became a guide for the
chemical identification of most of the subsequent members of the actinide
series. The series was predicted to end at element 103, and the subsequent
investigations confirmed this.
At element 104 (now known as rutherfordium), we jumped back up to the body of
the periodic table, and rutherfordium took its place under hafnium (element 72).
(This spot had been occupied by thorium before I moved it to a separate row at
the bottom of the periodic table). Then we proceed across the periodic table
along now-known elements 105-112, to undiscovered elements 113-118; element 118
will be a noble gas.
This form of the periodic table is accepted throughout the world and is now
ubiquitous in wall charts and chemistry books. I am, needless to say, proud that
U.S. chemists recommended that element 106, which is placed under tungsten (74),
be called "seaborgium." I am looking forward to the day when chemical
investigators will refer to such compounds as seaborgous chloride, seaborgic
nitrate, and perhaps, sodium seaborgate. Fortunately, this name, after initial
rejection, is now being accepted by the Commission on Nomenclature on Inorganic
Chemistry of the Union of Pure & Applied Chemistry (IUPAC).
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